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Os 30 maiores clássicos de Química Orgânica 1 & 2
Todos os mecanismos que você vai precisar desenhar neste ano — SN1, SN2, E1, E2, Diels–Alder, Grignard, aldol, Wittig e mais 22 — no aprendiz interativo do Arrow Lab: você faz cada seta, cada movimento é verificado e há dicas quando você travar.
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Os 30 mecanismos
- SN2 — SN2 substitution — 2-bromobutane and hydroxide
- SN1 with a 1,2-shift — SN1 substitution — a 1,2-hydride shift on the way
- E2 — E2 elimination — 2-bromobutane to but-2-ene
- E1 — E1 elimination — 1-methylcyclohexene
- Markovnikov hydration with a hydride shift — Markovnikov hydration — with a hydride shift
- Hydroboration (syn B–H addition) — Hydroboration — syn addition of B–H
- Br₂ addition (bromonium) — Bromine addition — through a bromonium ion
- Halohydrin — Halohydrin formation — styrene, Br₂ and water
- Epoxidation — Prilezhaev epoxidation — E-but-2-ene
- Allylic radical bromination — Allylic bromination — radical at the far end
- Acetylide alkylation — Acetylide alkylation — propyne to pent-2-yne
- Alcohol dehydration — Alcohol dehydration — propan-2-ol to propene
- Alcohol → alkyl bromide (PBr₃) — Alcohol to alkyl bromide — PBr₃
- Williamson ether synthesis — Williamson ether synthesis — alcohol activation and allylation
- Acid-catalysed epoxide opening — Epoxide opening — acid-catalysed, with methanol
- Base epoxide opening — Epoxide opening — with cyanide
- Diels–Alder — Diels–Alder reaction — an alkyne dienophile
- EAS nitration — Electrophilic aromatic substitution — nitration
- EAS bromination — Electrophilic aromatic substitution — bromination of anisole
- Friedel–Crafts acylation — Friedel–Crafts acylation — acylium capture
- Grignard addition — Grignard addition — ethylmagnesium bromide and acetone (mechanism)
- NaBH₄ reduction — NaBH₄ reduction — benzaldehyde to benzyl alcohol
- Wittig — Wittig reaction — butanal to pent-1-ene
- Acetal formation — Acetal formation — ethanal and methanol
- Imine formation — Imine formation — ethanal and ammonia
- Aldol condensation — Aldol condensation — dehydration of the aldol product
- Claisen condensation — Claisen condensation — enolate acyl addition and elimination
- Michael addition — Michael addition — malonate and methyl vinyl ketone
- Acid chloride → amide — Amide formation — acetyl chloride and methylamine
- Saponification — Saponification — methyl acetate and hydroxide
Quer todos os mecanismos, e não só 30?
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